MAGNEŢI MOLECULARI – TRECEREA DE LA LIGANZI DE TIP SALEN SPRE TIOSEMICARBAZONE

Mihail SECU Universitatea de Stat din Moldova

Abstract

SINGLE MOLECULE MAGNETS – SWITCHING FROM SALEN TYPE LIGANDS TO THIOSEMICARBAZONES

There were highlighted manganese(III) coordination compounds with Salen type ligands, which exhibit single molecule magnet (SMM) and single chain magnet (SCM) behaviour. It was narrated the principle of assembly bis(salicylidene)isothiosemicarbazide similar with Salen type ligands, for identify and describe the new methods of rational synthesis of single molecule magnets and single chain magnets, which have as building blocks these manganese(III) complexes. Keywords: Salen type ligands, single molecule magnet (SMM), single chain magnet (SCM), manganese(III) coordination compounds, bis(salicylidene)isothiosemicarbazide.